Vis enkel innførsel

dc.contributor.authorGevorgyan, Ashot
dc.contributor.authorHopmann, Kathrin Helen
dc.contributor.authorBayer, Annette
dc.date.accessioned2020-06-26T12:27:39Z
dc.date.available2020-06-26T12:27:39Z
dc.date.issued2020-01-07
dc.description.abstractA range of hitherto unexplored biomass‐derived chemicals have been evaluated as new sustainable solvents for a large variety of CO<sub>2</sub>‐based carboxylation reactions. Known biomass‐derived solvents (biosolvents) are also included in the study and the results are compared with commonly used solvents for the reactions. Biosolvents can be efficiently applied in a variety of carboxylation reactions, such as Cu‐catalyzed carboxylation of organoboranes and organoboronates, metal‐catalyzed hydrocarboxylation, borocarboxylation, and other related reactions. For many of these reactions, the use of biosolvents provides comparable or better yields than the commonly used solvents. The best biosolvents identified are the so far unexplored candidates isosorbide dimethyl ether, acetaldehyde diethyl acetal, rose oxide, and eucalyptol, alongside the known biosolvent 2‐methyltetrahydrofuran. This strategy was used for the synthesis of the commercial drugs Fenoprofen and Flurbiprofen.en_US
dc.identifier.citationGevorgyan A, Hopmann KH, Bayer A. Exploration of New Biomass-Derived Solvents: Application to Carboxylation Reactions. ChemSusChem. 2020en_US
dc.identifier.cristinIDFRIDAID 1768335
dc.identifier.doi10.1002/cssc.201903224
dc.identifier.issn1864-5631
dc.identifier.issn1864-564X
dc.identifier.urihttps://hdl.handle.net/10037/18675
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.journalChemSusChem
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2020 The Author(s)en_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.titleExploration of New Biomass-Derived Solvents: Application to Carboxylation Reactionsen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


Tilhørende fil(er)

Thumbnail

Denne innførselen finnes i følgende samling(er)

Vis enkel innførsel