Blar i forfatter Artikler, rapporter og annet (kjemi) "Rahman, Md. Hafizur"

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    • Infrared Spectroelectrochemistry of Iron-Nitrosyl Triarylcorroles. Implications for Ligand Noninnocence 

      Rahman, Md. Hafizur; Ryan, Michael D.; Vazquez-Lima, Hugo; Alemayehu, Abraham; Ghosh, Abhik (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-02-13)
      Recent DFT calculations have suggested that iron nitrosyl triarylcorrole complexes have substantial {FeNO}<sup>7</sup> −corrole<sup>•2−</sup> character. With this formulation, reduction of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole macrocycle rather than on the {FeNO}<sup>7</sup> moiety. To verify this proposition, visible and infrared spectroelectrochemical ...