Show simple item record

dc.contributor.authorSomerville, Rosie J.
dc.contributor.authorOdena, Carlota
dc.contributor.authorObst, Marc
dc.contributor.authorHazari, Nilay
dc.contributor.authorHopmann, Kathrin Helen
dc.contributor.authorMartin, Ruben
dc.date.accessioned2021-10-21T07:29:08Z
dc.date.available2021-10-21T07:29:08Z
dc.date.issued2020-06-10
dc.description.abstractAlthough the catalytic carboxylation of unactivated alkyl electrophiles has reached remarkable levels of sophistication, the intermediacy of (phenanthroline)Ni(I)–alkyl species—complexes proposed in numerous Ni-catalyzed reductive cross-coupling reactions—has been subject to speculation. Herein we report the synthesis of such elusive (phenanthroline)Ni(I) species and their reactivity with CO<sub>2</sub>, allowing us to address a long-standing question related to Ni-catalyzed carboxylation reactions.en_US
dc.identifier.citationSomerville, Odena, Obst FM, Hazari N, Hopmann KH, Martin. Ni(I)–Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers. Journal of the American Chemical Society. 2020en_US
dc.identifier.cristinIDFRIDAID 1815984
dc.identifier.doihttps://doi.org/10.1021/jacs.0c04695
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.urihttps://hdl.handle.net/10037/22797
dc.language.isoengen_US
dc.publisherACS Publicationsen_US
dc.relation.journalJournal of the American Chemical Society
dc.relation.projectIDNordforsk: 85378en_US
dc.relation.projectIDTromsø forskningsstiftelse: TFS2016KHHen_US
dc.relation.projectIDNotur/NorStore: nn4654ken_US
dc.relation.projectIDNorges forskningsråd: 262695en_US
dc.relation.projectIDNotur/NorStore: nn9330ken_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/SFF/262695/Norway/Hylleraas Centre for Quantum Molecular Sciences//en_US
dc.rights.accessRightsopenAccessen_US
dc.rights.holder© 2020 American Chemical Societyen_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.titleNi(I)–Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centersen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


File(s) in this item

Thumbnail

This item appears in the following collection(s)

Show simple item record