Since the discovery of decamethylsilicocene over three decades ago, chemists have successfully isolated a variety of divalent silicon compounds by orchestrating steric and electronic effects to their advantage. Two broad strategies of electronic stabilization appear to have been widely deployed, namely, π-conjugation as in diaminosilylenes and π-complexation as in decamethylsilicocene and ...

The article is a public policy analysis of the development of legislation on critical infrastructure in the European Union (EU), covering 27 developed countries. More precisely, it concerns the 2022 CER Directive “on the resilience of critical entities’. This directive replaced the 2008 ECI Directive ‘on the identification and designation of European critical infrastructure and the assessment of ...

This article discusses critical infrastructure resilience in terms of how it could be incorporated into the existing safety and security practices, namely the ISO 31000 risk management standard. The article starts by outlining the resilience discourse, focusing on the organizational, technological, and societal domains of resilience. It goes on to present an approach to how the risk management ...

In the Devonian–Carboniferous, a rapid succession of clustered extensional and contractional tectonic events is thought to have affected sedimentary rocks in central Spitsbergen, Svalbard. These events include Caledonian post-orogenic extensional collapse associated with the formation of thick Early–Middle Devonian basins, Late Devonian–Mississippian Ellesmerian contraction, and Early–Middle ...

New techniques in core–electron spectroscopy are necessary to resolve the structures of oxides of f-elements and other strongly correlated materials that are present only as powders and not as single crystals. Thus, accurate quantum chemical methods must be developed to calculate core spectroscopic properties in such materials. In this contribution, we present an important development in this ...

We present the extension of the quantum/classical polarizable fluctuating charge model to the calculation of single residues of quadratic response functions, as required for the computational modeling of two-photon absorption cross sections. By virtue of a variational formulation of the quantum/classical polarizable coupling, we are able to exploit an atomic orbital-based quasienergy formalism to ...

Nucleic acid-interacting proteins are essential players in cellular processes of all living organisms. In the present study, we explore three psychrophilic-derived proteins involved in gene regulation, RNA degradation and DNA ligation in bacterial cells, with one common feature; they perform their activity by interacting with nucleic acids. The Ferric uptake regulator (Fur) is a global transcription ...

A key challenge in genetics is identifying the functional roles of genes in pathways. Numerous functional genomics techniques (e.g. machine learning) that predict protein function have been developed to address this question. These methods generally build from existing annotations of genes to pathways and thus are often unable to identify additional genes participating in processes that are not ...

The objective of this master's thesis is to investigate the current and future technical and economic feasibility of PV systems for marine applications. Two scenarios will be studied; a land-based PV power station to supply an in-land ferry in Norway and a PV system installed on a wind farm support vessel as a supplementary power source. The two scenarios are use cases that support the two research ...

Den polare atmosfæren har fått mer oppmerksomhet i den senere tid enn den vanligvis har vært forunt. Dette henger sammen med tanken om at den er så ren og upåvirket av eventuelle forurensninger som vi pumper ut i atmosfæren i de mer urbane strøk. Dersom atmosfæren tar skade av denne aktiviteten, forventer en å se skadevirkningene først og klarest i den polare atmosfæren. Svekkelsen av ozonlaget ...