First principles theoretical modeling of out-of-equilibrium processes observed in attosecond pump–probe transient absorption spectroscopy (TAS) triggering pure electron dynamics remains a challenging task, especially for heavy elements and/or core excitations containing fingerprints of scalar and spin–orbit relativistic effects. To address this, we formulate a methodology for simulating TAS within ...

Sea ice drift and deformation, namely sea ice dynamics, play a significant role in atmosphere–ice–ocean coupling. Deformation patterns in sea ice can be observed over a wide range of spatial and temporal scales, though high-resolution objective quantification of these features remains difficult. In an effort to better understand local deformation of sea ice, we adapt the trajectory-stretching exponents ...

Per- and polyfluoroalkyl substances (PFAS) are stable organic chemicals, which have been used globally since the 1940s and have caused PFAS contamination around the world. This study explores perfluorooctanoic acid (PFOA) enrichment and destruction by a combined method of sorption/desorption and photocatalytic reduction. A novel biosorbent (PG-PB) was developed from raw pine bark by grafting amine ...

Sunspot records reveal that whilst the Sun has an approximately 11 year cycle of activity, no two cycles are of the same duration. Since this activity is a direct driver of space weather at Earth, this presents an operational challenge to quantifying space weather risk. We recently showed that the Hilbert transform of the sunspot record can be used to map the variable cycle length onto a regular ...

Annotated clinical text corpora are essential for machine learning studies that model and predict care processes and disease progression. However, few studies describe the necessary experimental design of the annotation guideline and annotation phases. This makes replication, reuse, and adoption challenging. Using clinical questions about sepsis, we designed a semantic annotation guideline to ...

This study aims to demonstrate the generation and detection of Scholte waves inside polystyrene microparticles. This was proven using both experimental analysis and COMSOL simulation. Microspheres of different sizes were excited optically with a pulsed laser (532 nm), and the acoustic signals were detected using a transducer (40 MHz). On analyzing the laser-generated ultrasound signals, the results ...

Sea-ice ridges constitute a large fraction of the ice volume in the Arctic Ocean, yet we know little about the evolution of these ice masses. Here we examine the thermal and morphological evolution of an Arctic firstyear sea-ice ridge, from its formation to advanced melt. Initially the mean keel depth was 5.6 m and mean sail height was 0.7 m. The initial rubble macroporosity (fraction of seawater ...

<p>The amounts of data in the world have increased dramatically in recent years, and it is quickly becoming infeasible for humans to label all these data. It is therefore crucial that modern machine learning systems can operate with few or no labels. The introduction of deep learning and deep neural networks has led to impressive advancements in several areas of machine learning. These advancements ...

During the Last Glacial Maximum (LGM), the Patagonian Ice Sheet (PIS) was the largest Quaternary ice mass in the Southern Hemisphere outside of Antarctica. Although the margins of the LGM ice sheet are now well established through end-moraine mapping and dating, apart from a few modelling and empirical studies, there remains a lack of constraint on its thickness and three-dimensional configuration. ...

High-quality density functional theory calculations underscore a nearly 6 eV range for the ionization potentials (IPs) of neutral, low-valent carbon compounds, including carbenes, ylides, and zero-valent carbon compounds (carbones) such as carbodiphosphoranes (CDPs) and carbodicarbenes. Thus, adiabatic IPs as low as 5.5 ± 0.1 eV are predicted for CDPs, which are about 0.7–1.2 eV lower than those of ...