A porphyrin cis tautomer, where the two central NH protons are on adjacent pyrrole rings, has long been invoked as an intermediate in porphyrin tautomerism. Only recently, however, has such a species been isolated and structurally characterized. Thus, single-crystal X-ray structure determinations of two highly saddled free-base porphyrins, β-heptakis(trifluoromethyl)-meso-tetrakis(p-fluorophenyl)porphyrin, ...

A combination of Cr K-edge XAS and DFT calculations have been performed on archetypal chromium porphyrinoid complexes Cr^IV[TMP]O (<b>2</b>) and Cr^V[TPC]O (<b>3</b>), and the results have been compared to the reference compound Cr^III[TPP]Cl (<b>1</b>), where TPP²⁻, TMP²⁻, and TPC³⁻ are the anions of <i>meso</i>-tetraphenylporphyrin, ...

Biological data is often visualized using networks. However, these networks face problems such as information overload, high interconnectivity, and high dimensionality. Existing approaches try to solve these problems by reducing the interactivity in favor of presenting more information or by using expensive hardware. This thesis aims to solve them using Virtual Reality (VR) and the Oculus Quest, an ...

While monitoring rodents in the Arctic Tundra to evaluate if climate changes affect the ecosystem. The camera-traps of the coat project generates image data in large scale each year. To manually examine the data in regards to label- ing is a tedious and time-consuming job, and a more efficient and automated tool for the task is required. In this thesis we presents the architecture, design and ...

In the European renewable energy portfolio, wind has a sizeable share in the total energy production. The Nordic and Baltic energy systems in particular are benefiting from wind energy to reach the greenhouse gas emissions reduction objectives set by the EU. The wind energy production varies with time, and this intermittent characteristic imposes a challenge for full utilization of renewable energy ...

Knowledge about frequency and location of snow avalanche activity is essential for forecasting and mapping of snow avalanche hazard. Traditional field monitoring of avalanche activity has limitations, especially when surveying large and remote areas. In recent years, avalanche detection in Sentinel-1 radar satellite imagery has been developed to improve monitoring. However, the current state-of-the-art ...

Image denoising or artefact removal using deep learning is possible in the availability of supervised training dataset acquired in real experiments or synthesized using known noise models. Neither of the conditions can be fulfilled for nanoscopy (super-resolution optical microscopy) images that are generated from microscopy videos through statistical analysis techniques. Due to several physical ...

Due to the increasing pressure from stricter environmental regulations to reduce emissions in shipping, the maritime industry has been striving for finding more effective measures. Existing measures are often not enough to comply with new regulations. Among various alternative measures, it is not easy for decision-makers (shipowners and operators) to choose the most suitable alternative measure as ...

Photonic-chip-based light illumination has recently found applications in optical microscopy and nanoscopy methodologies. The photonic chip removes the dependency on imaging objective lenses to generate the required illumination patterns for different microscopy methods. Until now, all the reported chip-based optical microscopy methods exploit the evanescent field present on top of a waveguide surface ...

Drone borne radar systems have seen considerable advances over recent years, and the application of drone-mounted continuous wave (CW) radars for remote sensing of snow properties has great potential. Regardless, major challenges remain in antenna design for which both low weight and small size combined with high gain and bandwidth are important design parameters. Additional limiting factors for CW ...