We have employed computational methods to investigate the iridium-catalyzed allylic substitution leading to the formation of enantioenriched allyl carbamates from carbon dioxide (CO₂). The reaction occurs in several steps, with initial formation of an iridium-allyl, followed by nucleophilic attack by the carbamate formed in situ from CO₂ and an amine. A detailed isomeric analysis ...

A novel experimental method based on the Coulomb coupling technique is used for visualizing the interaction of ultrasonic waves in PZT (Lead Zirconate Titanate - (Pb[ZrxTi1-x]O3 (0 ≤ x ≤ 1)) ceramic materials. The method of excitation and detection through a point contact produces representations of propagating wave vectors in the time domain as a series of images. In the acoustic image, several ...

Sedimentary records of Early Pleistocene (~2.6–0.8 Ma) glaciations are sparse on shelves, yet trough mouth fans on adjacent continental slopes provide a continuous record of ice-sheet and climate development throughout the Quaternary. Here, we interpret high-quality 3D seismic reflection data combined with borehole and chronostratigraphic information from a shelf-slope setting in the southwestern ...

International Ocean Discovery Program (IODP) Expedition 374 sailed to the Ross Sea in 2018 to reconstruct paleoenvironments, track the history of key water masses, and assess model simulations that show warm-water incursions from the Southern Ocean led to the loss of marine-based Antarctic ice sheets during past interglacials. IODP Site U1523 (water depth 828 m) is located at the continental shelf ...

Silicon compounds containing silicon–silicon bond with a variety of unusual oxidation states are quite important, because their high reactivity leads to the formation of a variety of silicon compounds. The isolation of such compounds with unusual oxidation states requires a resilient synthetic strategy. Herein, we report the synthesis of a silicon based spirocyclic compound containing a hyper-valent ...

Over recent years, we have been living under a pandemic, caused by the rapid spread of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV2). One of the major virulence factors of Coronaviruses is the Non-structural protein 1 (Nsp1), known to suppress the host cells protein translation machinery, allowing the virus to produce its own proteins, propagate and invade new cells. To ...

This thesis builds an evolutionary history of recent times for a region of the Southern Vøring margin west of the Vigrid Syncline, focusing mainly on the morphological traits of mass-transport complexes and selected internal structures. The scenario covers the last 0.8 million years, the three later periods of Naust time. Preliminary research was done on pertinent geological processes and features ...

Svalbard has long been thought to represent the easternmost realm of the Ellesmerian Orogeny in the late Devonian or early Mississippian (Svalbardian tectonic event). Several authors do not agree and present alternative interpretations of the observed structures in older and more recent articles. This article discusses a number of issues that, in our opinion, are not sufficiently considered in ...

Etter innføringen av Læreplanverket for Kunnskapsløftet i 2020 (LK20) har åpne oppgaver fått en større plass i matematikkfaget, noe som kommer til syne både på halvårsvurderinger utviklet av ulike forlag og på eksamensoppgaver i matematikk for 10. trinn. Mine erfaringer fra praksisperioder i studietiden har gjort meg oppmerksom og nysgjerrig på hvordan åpne oppgaver vurderes. Denne masterstudien ...

Objective: Clinical data analysis relies on effective methods and appropriate data. Recognizing distinctive clinical services and service functions may lead to improved decision-making. Our first objective is to categorize analytical methods, data sources, and algorithms used in current research on information analysis and decision support in child and adolescent mental health services (CAMHS). ...