A highly asymmetric gold(III) η3‐allyl complex
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https://hdl.handle.net/10037/17217Dato
2019-11-11Type
Journal articleTidsskriftartikkel
Peer reviewed
Sammendrag
A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature 1H NMR suggest that the allyl ligand is highly fluxional.
Forlag
WileySitering
Holmsen MS, Nova A, Øien-Ødegaard S, Heyn RH, Tilset M. A highly asymmetric gold(III) η3‐allyl complex. Angewandte Chemie International Edition. 2019:1-6Metadata
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