A highly asymmetric gold(III) η3‐allyl complex

Permanent lenke
https://hdl.handle.net/10037/17217
DOI
https://doi.org/10.1002/anie.201912315
Thumbnail
Åpne
Publisert versjon (PDF)
Dato
2019-11-11
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Forfatter
Holmsen, Marte Sofie; Nova, Ainara; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats
Sammendrag
A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature 1H NMR suggest that the allyl ligand is highly fluxional.
Forlag
Wiley
Sitering
Holmsen MS, Nova A, Øien-Ødegaard S, Heyn RH, Tilset M. A highly asymmetric gold(III) η3‐allyl complex. Angewandte Chemie International Edition. 2019:1-6
Metadata
Vis full innførsel
Samlinger
Copyright 2019 The Author(s)