Platinum Corroles

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https://hdl.handle.net/10037/7899
DOI
https://doi.org/10.1039/c4cc02548b
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Date
2014-06-09
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Author
Alemayehu, Abraham; Vazquez-Lima, Hugo; Beavers, Christine M.; Gagnon, Kevin J.; Bendix, Jesper; Ghosh, Abhik
Abstract
Platinum has been inserted into corroles for the first time and three oxidized PtIV(corrole2)ArAr0 complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl - corrole2 charge transfer character in these transitions.
Publisher
Royal Society of Chemistry
Citation
Chemical Communications 50(2014) nr. 11093 s. 11093-11096
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