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One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction.

dc.contributor.authorNorheim, Hans-Kristian
dc.contributor.authorSchneider, Christian
dc.contributor.authorGagnon, Kevin J.
dc.contributor.authorGhosh, Abhik
dc.date.accessioned2018-03-06T11:03:44Z
dc.date.available2018-03-06T11:03:44Z
dc.date.issued2017-02-14
dc.description.abstractA one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris (2,6-dibromo-3,5-dimethoxyphenyl) corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to MnIII and AuIII. A single-crystal X-ray structure was obtained for the MnIII complex.en_US
dc.description.sponsorshipThe Advanced Light Source, Berkeley, California (US Department of Energy): DE-AC02-05CH11231en_US
dc.descriptionSource at: <a href=https://doi.org/10.1002/open.201600168> https://doi.org/10.1002/open.201600168 </a>en_US
dc.identifier.citationNorheim, H.-K., Schneider, C., Gagnon, K. J., Ghosh, A. (2017) One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction. ChemistryOpen, 6(2), 221-225. https://doi.org/10.1002/open.201600168en_US
dc.identifier.cristinIDFRIDAID 1544151
dc.identifier.doi10.1002/open.201600168
dc.identifier.issn2191-1363
dc.identifier.urihttps://hdl.handle.net/10037/12260
dc.language.isoengen_US
dc.publisherWiley Open Accessen_US
dc.relation.journalChemistryOpen
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/FRINATEK/231086/Norway/Corroles as a Platform for Fundamental Transition Metal Chemistry, with Emphasis on Heavy Elements//en_US
dc.rights.accessRightsopenAccessen_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.titleOne-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction.en_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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