dc.contributor.author | Vaitla, Janakiram | |
dc.contributor.author | Guttormsen, Yngve | |
dc.contributor.author | Mannisto, Jere K. | |
dc.contributor.author | Nova, Ainara | |
dc.contributor.author | Repo, Timo | |
dc.contributor.author | Bayer, Annette | |
dc.contributor.author | Hopmann, Kathrin Helen | |
dc.date.accessioned | 2018-09-10T12:10:18Z | |
dc.date.available | 2018-09-10T12:10:18Z | |
dc.date.issued | 2017-09-09 | |
dc.description.abstract | CO<sub>2</sub> is a promising and sustainable carbon feedstock for organic synthesis. New catalytic protocols for efficient incorporation of CO<sub>2</sub>into organic molecules are continuously being reported. However, little progress has been made in the enantioselective conversion of CO<sub>2</sub>to form enantioenriched molecules. In order to allow CO<sub>2</sub>to become a versatile carbon source in academia and in the fine chemical and pharmaceutical industries, the development of enantioselective approaches is essential. Here we discuss general strategies for CO<sub>2</sub>activation and for generation of enantioenriched molecules, alongside selected examples of reactions involving asymmetric incorporation of CO<sub>2</sub>. The main product classes considered are carboxylic acids and derivatives (C–CO<sub>2</sub>bonds) and carbonates, carbamates, and polycarbonates (C–OCO bonds). Similarities to asymmetric hydrogenation are discussed, and some strategies for developing novel enantioselective CO<sub>2</sub>reactions are outlined. | en_US |
dc.description.sponsorship | Tromsø Research Foundation
Magnus Ehrnrooth Foundation | en_US |
dc.description | This document is the Accepted Manuscript version of a Published Work that appeared in final form in <i>ACS Catalysis</i>, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see <a href=https://doi.org/10.1021/acscatal.7b02306> https://doi.org/10.1021/acscatal.7b02306</a>. | en_US |
dc.identifier.citation | Vaitla, J., Guttormsen, Y., Mannisto, J.K., Nova, A., Repo, T., Bayer, A. & Hopmann, K.H. (2017). Enantioselective incorporation of CO2: status and potential. ACS Catalysis, 7(10), 7231-7244. https://doi.org/10.1021/acscatal.7b02306 | en_US |
dc.identifier.cristinID | FRIDAID 1495918 | |
dc.identifier.doi | 10.1021/acscatal.7b02306 | |
dc.identifier.issn | 2155-5435 | |
dc.identifier.uri | https://hdl.handle.net/10037/13741 | |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.relation.journal | ACS Catalysis | |
dc.relation.projectID | info:eu-repo/grantAgreement/RCN/FRINATEK/231706/Norway/"Eeny, meeny, miny, moe": Selectivity-determining factors in asymmetric catalysis// | en_US |
dc.relation.projectID | info:eu-repo/grantAgreement/RCN/SFF/179568/Norway/Centre for Theoretical and Computational Chemistry/CTCC/ | en_US |
dc.relation.projectID | info:eu-repo/grantAgreement/RCN/FRINATEK/250044/Norway/Rational catalyst design for transforming CO2 into industrially attractive products: Formic acid, polycarbonates and polyurethanes// | en_US |
dc.relation.uri | http://pubs.acs.org/articlesonrequest/AOR-j3TZbtYF3PxdiITGtc5Z | |
dc.rights.accessRights | openAccess | en_US |
dc.subject | VDP::Matematikk og Naturvitenskap: 400::Kjemi: 440 | en_US |
dc.subject | VDP::Mathematics and natural science: 400::Chemistry: 440 | en_US |
dc.subject | asymmetric synthesis | en_US |
dc.subject | carbamate | en_US |
dc.subject | carbonate | en_US |
dc.subject | carboxylic acid | en_US |
dc.subject | catalysis | en_US |
dc.subject | CO2 | en_US |
dc.subject | enantioselectivity | en_US |
dc.title | Enantioselective incorporation of CO2: status and potential | en_US |
dc.type | Journal article | en_US |
dc.type | Tidsskriftartikkel | en_US |
dc.type | Peer reviewed | en_US |