dc.contributor.author | Gevorgyan, Ashot | |
dc.contributor.author | Mkrtchyan, Satenik | |
dc.contributor.author | Grigoryan, Tatevik | |
dc.contributor.author | Iaroshenko, Viktor O | |
dc.date.accessioned | 2019-01-21T08:30:20Z | |
dc.date.available | 2019-01-21T08:30:20Z | |
dc.date.issued | 2018-04-06 | |
dc.description.abstract | The use of water as a donor for hydrogen suitable for the reduction of several important classes of organic compounds is described. It is found that the reductive water splitting can be promoted by several metalloids among which silicon shows the best efficiency. The developed methodologies were applied for the reduction of nitro compounds, N‐oxides, sulfoxides, alkenes, alkynes, hydrodehalogenation as well as for the gram‐scale synthesis of several substrates of industrial importance. | en_US |
dc.description.sponsorship | Polish National Center of Sciences | en_US |
dc.description | This is the peer reviewed version of the following article: Gevorgyan, A., Mkrtchyan, S., Grigoryan, T. & Iaroshenko, V.O. (2018). Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates. <i>ChemPlusChem, 83</i>(5), 375-382, which has been published in final form at <a href=https://doi.org/10.1002/cplu.201800131> https://doi.org/10.1002/cplu.201800131</a>. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | en_US |
dc.identifier.citation | Gevorgyan, A., Mkrtchyan, S., Grigoryan, T. & Iaroshenko, V.O. (2018). Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates. <i>ChemPlusChem, 83</i>(5), 375-382. https://doi.org/10.1002/cplu.201800131 | en_US |
dc.identifier.cristinID | FRIDAID 1630511 | |
dc.identifier.doi | 10.1002/cplu.201800131 | |
dc.identifier.issn | 2192-6506 | |
dc.identifier.uri | https://hdl.handle.net/10037/14492 | |
dc.language.iso | eng | en_US |
dc.publisher | Wiley | en_US |
dc.relation.journal | ChemPlusChem | |
dc.rights.accessRights | openAccess | en_US |
dc.subject | VDP::Mathematics and natural science: 400::Chemistry: 440 | en_US |
dc.subject | VDP::Matematikk og Naturvitenskap: 400::Kjemi: 440 | en_US |
dc.subject | catalysis | en_US |
dc.subject | silicon | en_US |
dc.subject | substrate scope | en_US |
dc.subject | transfer hydrogenation | en_US |
dc.subject | water splitting | en_US |
dc.title | Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates | en_US |
dc.type | Journal article | en_US |
dc.type | Tidsskriftartikkel | en_US |
dc.type | Peer reviewed | en_US |