Rahman, Md. Hafizur; Ryan, Michael D.; Vazquez-Lima, Hugo; Alemayehu, Abraham; Ghosh, Abhik (Journal article; Tidsskriftartikkel; Peer reviewed, 2020-02-13)
Recent DFT calculations have suggested that iron nitrosyl triarylcorrole
complexes have substantial {FeNO}<sup>7</sup>
−corrole<sup>•2−</sup> character. With this formulation, reduction
of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole
macrocycle rather than on the {FeNO}<sup>7</sup> moiety. To verify this proposition, visible and
infrared spectroelectrochemical ...