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Regioselective formylation of rhenium-oxo and gold corroles: Substituent effects on optical spectra and redox potentials

dc.contributor.authorEinrem, Rune F.
dc.contributor.authorJonsson, Einar Torfi
dc.contributor.authorTeat, Simon J.
dc.contributor.authorSettineri, Nicholas S.
dc.contributor.authorAlemayehu, Abraham B.
dc.contributor.authorGhosh, Abhik
dc.date.accessioned2022-02-02T09:00:00Z
dc.date.available2022-02-02T09:00:00Z
dc.date.issued2021-10-28
dc.description.abstractVilsmeier–Haack formylation of ReO and Au meso-triarylcorroles over 16–18 hours affords moderate to good yields (47–65%) of the ReO-3-formyl and Au-3,17-diformyl derivatives in a highly regioselective manner. Formylation was found to effect substantial upshifts for redox potentials (especially the reduction potentials) as well as significant to dramatic redshifts for both the Soret and Q bands.en_US
dc.identifier.citationEinrem, Jonsson, Teat, Settineri, Alemayehu, Ghosh. Regioselective formylation of rhenium-oxo and gold corroles: Substituent effects on optical spectra and redox potentials. RSC Advances. 2021;11(54):34086-34094en_US
dc.identifier.cristinIDFRIDAID 1967570
dc.identifier.doi10.1039/d1ra05525a
dc.identifier.issn2046-2069
dc.identifier.urihttps://hdl.handle.net/10037/23887
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofEinrem, R.F. (2023). New Building Blocks for Cancer Phototherapeutics: 5d Metallocorroles. (Doctoral thesis). <a href=https://hdl.handle.net/10037/28538>https://hdl.handle.net/10037/28538</a>.
dc.relation.journalRSC Advances
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/NANO2021/262229/Norway/Metallocorroles for photodynamic therapy and bioimaging//en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/NANO2021/324139Norway/Synchrotron-Assisted Design of Cancer Phototherapeutics//en_US
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2021 The Author(s)en_US
dc.titleRegioselective formylation of rhenium-oxo and gold corroles: Substituent effects on optical spectra and redox potentialsen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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