Blar i forfatter Doktorgradsavhandlinger (NT-fak) "Capar, Jan"
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Synthesis of Sterically Hindered Macrocyclic Ligands via Demetalation of Metallocorroles
Capar, Jan (Doctoral thesis; Doktorgradsavhandling, 2016-06-07)Despite important developments in synthetic corrole chemistry, the field has long been handicapped by the lack of procedures for demetalation of metallocorroles. This thesis presents general demetalation methods for metallocorroles. A reductive demetalation method was developed using concentrated H2SO4 with 5-200 equivalent of FeCl2 or SnCl2 as a reducing agent. The method proved to be quite general ...