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dc.contributor.authorJohannessen, Krister Engedal
dc.contributor.authorJohansen, Martin Amund Langaas
dc.contributor.authorEinrem, Rune Finsås
dc.contributor.authorMcCormick McPherson, Laura J.
dc.contributor.authorAlemayehu, Abraham
dc.contributor.authorBorisov, Sergey M.
dc.contributor.authorGhosh, Abhik
dc.date.accessioned2023-11-23T10:45:04Z
dc.date.available2023-11-23T10:45:04Z
dc.date.issued2023-07-12
dc.description.abstractThe influence of fluorinated substituents on the luminescent properties of rhenium-oxo, osmium-nitrido, and gold triarylcorroles was studied via a comparison of four ligands: triphenylcorrole (TPC), tris(ptrifluoromethylphenyl)corrole (TpCF<sub>3</sub>PC), tris{3,5-bis(trifluoromethyl)- phenyl}corrole (T3,5-CF<sub>3</sub>PC), and tris(pentafluorophenyl)corrole (TPFPC). For each metal series examined, fluorinated substituents were found to enhance the luminescent properties, with the phosphorescence quantum yields and triplet decay times increasing in the order TPC < TpCF<sub>3</sub>PC < T3,5-CF<sub>3</sub>PC < TPFPC. Among the 11 complexes examined, the highest phosphorescence quantum yield, 2.2%, was recorded for Re[TPFPC](O).en_US
dc.identifier.citationJohannessen, Johansen, Einrem, McCormick McPherson, Alemayehu, Borisov, Ghosh. Influence of Fluorinated Substituents on the Near-Infrared Phosphorescence of 5d Metallocorroles. ACS Organic & Inorganic Au. 2023en_US
dc.identifier.cristinIDFRIDAID 2180315
dc.identifier.doi10.1021/acsorginorgau.3c00016
dc.identifier.issn2694-247X
dc.identifier.urihttps://hdl.handle.net/10037/31865
dc.language.isoengen_US
dc.publisherACS Publicationsen_US
dc.relation.journalACS Organic & Inorganic Au
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2023 The Author(s)en_US
dc.rights.urihttps://creativecommons.org/licenses/by/4.0en_US
dc.rightsAttribution 4.0 International (CC BY 4.0)en_US
dc.titleInfluence of Fluorinated Substituents on the Near-Infrared Phosphorescence of 5d Metallocorrolesen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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Attribution 4.0 International (CC BY 4.0)
Except where otherwise noted, this item's license is described as Attribution 4.0 International (CC BY 4.0)