Larsen, Simon; Adewuyi, Joseph A.; Ung, Gaël; Ghosh, Abhik (Journal article; Tidsskriftartikkel; Peer reviewed, 2023-05-04)
Building on a highly efficient synthesis of pyrrole-appended isocorroles,
we have worked out conditions for manganese, palladium, and platinum insertion into
free-base 5/10-(2-pyrrolyl)-5,10,15-tris(4-methylphenyl)isocorrole, H<sub>2</sub>[5/10-(2-py)-
TpMePiC]. Platinum insertion proved exceedingly challenging but was finally
accomplished with cis-Pt(PhCN)<sub>2</sub>Cl<sub>2</sub>. All the ...