Palladium(0)-Catalyzed Cross-Couplings of 2-Bromophosphinine

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https://hdl.handle.net/10037/9746
DOI
https://doi.org/10.1002/ejoc.201300710
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Accepted manuscript version (PDF)
Date
2013-05-21
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Author
Kostenko, Nataliya; Eriksson, Cecilia; Engqvist, Magnus; Villa Gonzalez, Susana; Bayer, Annette
Abstract
A new Negishi-type cross-coupling of 2-bromophosphinine has been developed. The new method expands the scope of palladium-catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl-, alkenyl-, and alkynylzinc bromides were found to be effective coupling partners.
Description
Accepted manuscript version. Publisher's version available at http://doi.org/10.1002/ejoc.201300710.
Publisher
ChemPubSoc Europe
Citation
European Journal of Organic Chemistry 2013 (22): 4756-4759
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