Palladium(0)-Catalyzed Cross-Couplings of 2-Bromophosphinine
Permanent lenke
https://hdl.handle.net/10037/9746Dato
2013-05-21Type
Journal articleTidsskriftartikkel
Peer reviewed
Forfatter
Kostenko, Nataliya; Eriksson, Cecilia; Engqvist, Magnus; Villa Gonzalez, Susana; Bayer, AnnetteSammendrag
A new Negishi-type cross-coupling of 2-bromophosphinine has been developed. The new method expands the scope of palladium-catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl-, alkenyl-, and alkynylzinc bromides were found to be effective coupling partners.
Beskrivelse
Accepted manuscript version. Publisher's version available at http://doi.org/10.1002/ejoc.201300710.