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Visible-light photocatalytic double C–H Functionalization of indoles: a synergistic experimental and computational study

dc.contributor.authorErdenebileg, Uranbaatar
dc.contributor.authorDemissie, Taye Beyene
dc.contributor.authorHansen, Jørn H
dc.date.accessioned2017-03-23T11:22:01Z
dc.date.available2017-03-23T11:22:01Z
dc.date.issued2017-02-21
dc.description.abstractHerein is disclosed a novel visible-light photocatalytic double C–H functionalization of indoles. The reaction affords 2,3-difunctional- ized indoles in up to 84% yield, but the reaction rate depends strongly on electronic substituent effects. Mechanistic DFT studies and control experiments suggest that the secondary functionalization occurs through an independent photocatalytic oxidation of bromide ions formed during the reaction to generate molecular bromine capable of electrophilic C-3 bromination.en_US
dc.descriptionPublished version. source at <a href=http://dx.doi.org/10.1055/s-0036-1588719> http://dx.doi.org/10.1055/s-0036-1588719 </a>en_US
dc.identifier.citationErdenebileg U, Demissie TB, Hansen JHH. Visible-light photocatalytic double C–H Functionalization of indoles: a synergistic experimental and computational study. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 2017en_US
dc.identifier.cristinIDFRIDAID 1440390
dc.identifier.issn0936-5214
dc.identifier.issn1437-2096
dc.identifier.urihttps://hdl.handle.net/10037/10845
dc.language.isoengen_US
dc.publisherThieme Publishingen_US
dc.relation.journalSynlett : Accounts and Rapid Communications in Synthetic Organic Chemistry
dc.rights.accessRightsopenAccessen_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440::Teoretisk kjemi, kvantekjemi: 444en_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440::Theoretical chemistry, quantum chemistry: 444en_US
dc.subjectphotocatalysisen_US
dc.subjectC–H functionalizationen_US
dc.subjectindolesen_US
dc.subjectDFTen_US
dc.subjectreaction mechanismen_US
dc.titleVisible-light photocatalytic double C–H Functionalization of indoles: a synergistic experimental and computational studyen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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