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Iron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study

Permanent link
https://hdl.handle.net/10037/14471
DOI
https://doi.org/10.1002/anie.201810451
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Date
2018-10-15
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Author
Vaitla, Janakiram; Bayer, Annette; Hopmann, Kathrin Helen
Abstract
A method for the generation of unprecedented vinyl carbenoids from sulfoxonium ylides has been developed and applied in the synthesis of a diverse array of heterocycles such as indolizines, pyrroles, 3‐pyrrolin‐2‐ones, and furans. The reactions proceed by FeBr2 catalysis under mild reaction conditions with a broad substrate scope. A reaction pathway involving iron carbenoids is proposed based on a series of control experiments and DFT calculations.
Description
This is the peer reviewed version of the following article: Vaitla, J., Bayer, A. & Hopmann, K.H. (2018). Iron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study. Angewandte Chemie International Edition, 57(49), 16180-16184, which has been published in final form at https://doi.org/10.1002/anie.201810451. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Publisher
Wiley
Citation
Vaitla, J., Bayer, A. & Hopmann, K.H. (2018). Iron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study. Angewandte Chemie International Edition, 57(49), 16180-16184. https://doi.org/10.1002/anie.201810451
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