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Iron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study

dc.contributor.authorVaitla, Janakiram
dc.contributor.authorBayer, Annette
dc.contributor.authorHopmann, Kathrin Helen
dc.date.accessioned2019-01-17T10:39:59Z
dc.date.available2019-01-17T10:39:59Z
dc.date.issued2018-10-15
dc.description.abstractA method for the generation of unprecedented vinyl carbenoids from sulfoxonium ylides has been developed and applied in the synthesis of a diverse array of heterocycles such as indolizines, pyrroles, 3‐pyrrolin‐2‐ones, and furans. The reactions proceed by FeBr<sub>2</sub> catalysis under mild reaction conditions with a broad substrate scope. A reaction pathway involving iron carbenoids is proposed based on a series of control experiments and DFT calculations.en_US
dc.description.sponsorshipTromsø Research Foundation Notur—The Norwegian Metacenter for Computational Science NordForsken_US
dc.descriptionThis is the peer reviewed version of the following article: Vaitla, J., Bayer, A. & Hopmann, K.H. (2018). Iron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study. <i>Angewandte Chemie International Edition, 57</i>(49), 16180-16184, which has been published in final form at <a href=https://doi.org/10.1002/anie.201810451> https://doi.org/10.1002/anie.201810451</a>. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.identifier.citationVaitla, J., Bayer, A. & Hopmann, K.H. (2018). Iron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study. <i>Angewandte Chemie International Edition, 57</i>(49), 16180-16184. https://doi.org/10.1002/anie.201810451en_US
dc.identifier.cristinIDFRIDAID 1621183
dc.identifier.doihttps://doi.org/10.1002/anie.201810451
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttps://hdl.handle.net/10037/14471
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.journalAngewandte Chemie International Edition
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/FRINATEK/231706/Norway/"Eeny, meeny, miny, moe": Selectivity-determining factors in asymmetric catalysis//en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/SFF/262695/Norway/Hylleraas Centre for Quantum Molecular Sciences//en_US
dc.relation.urihttps://doi.org/10.1002/anie.201810451
dc.rights.accessRightsopenAccessen_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.subjectcarbenoidsen_US
dc.subjectheterocyclesen_US
dc.subjectironen_US
dc.subjectsynthetic methodsen_US
dc.subjectylidesen_US
dc.titleIron‐Catalyzed Carbenoid Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Studyen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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