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dc.contributor.authorGevorgyan, Ashot
dc.contributor.authorObst, Marc
dc.contributor.authorGuttormsen, Yngve
dc.contributor.authorMaseras, Feliu
dc.contributor.authorHopmann, Kathrin Helen
dc.contributor.authorBayer, Annette
dc.date.accessioned2019-11-11T14:36:10Z
dc.date.available2019-11-11T14:36:10Z
dc.date.issued2019-09-11
dc.description.abstractA caesium fluoride-mediated hydrocarboxylation of olefins is disclosed that does not rely on precious transition metal catalysts and ligands. The reaction occurs at atmospheric pressures of CO<sub>2</sub> in the presence of 9-BBN as a stoichiometric reductant. Stilbenes, β-substituted styrenes and allenes could be carboxylated in good yields. The developed methodology can be used for preparation of commercial drugs as well as for gram scale hydrocarboxylation. Computational studies indicate that the reaction occurs via formation of an organocaesium intermediate.en_US
dc.identifier.citationGevorgyan, A., Obst, M.F., Guttormsen, Y., Maseras, F., Hopmann, K.H. & Bayer, A. (2019). Caesium Fluoride-Mediated Hydrocarboxylation of Alkenes and Allenes: Scope and Mechanistic Insights. <i>Chemical Science, 10</i>(43), 10072-10078. https://dx.doi.org/10.1039/C9SC02467Ken_US
dc.identifier.cristinIDFRIDAID 1724671
dc.identifier.doi10.1039/C9SC02467K
dc.identifier.issn2041-6520
dc.identifier.issn2041-6539
dc.identifier.urihttps://hdl.handle.net/10037/16647
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofObst, M. (2020). Homogeneous Metal-Mediated Carboxylation with Carbon Dioxide. (Doctoral thesis). <a href=https://hdl.handle.net/10037/18958>https://hdl.handle.net/10037/18958</a>.
dc.relation.journalChemical Science
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/SFF/262695/Norway/Hylleraas Centre for Quantum Molecular Sciences//en_US
dc.rights.accessRightsopenAccessen_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.titleCaesium Fluoride-Mediated Hydrocarboxylation of Alkenes and Allenes: Scope and Mechanistic Insightsen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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