Platinum corroles

Permanent link
https://hdl.handle.net/10037/25265
DOI
https://doi.org/10.1039/c4cc02548b
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Date
2014-06-09
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Author
Alemayehu, Abraham; Lima, Hugo Vazquez; Beavers, Christine M.; Gagnon, Kevin J.; Bendix, Jesper; Ghosh, Abhik
Abstract
Platinum has been inserted into corroles for the first time and three oxidized PtIV(corrole2-)ArAr0 complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl - corrole2- charge transfer character in these transitions.
Publisher
Royal Society of Chemistry
Citation
Alemayehu A, Lima H, Beavers CM, Gagnon, Bendix, Ghosh A. Platinum corroles. Chemical Communications. 2014
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Copyright 2014 The Royal Society of Chemistry