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Room Temperature-Stable Magnesium Electride via Ni(II) Reduction

dc.contributor.authorDo, Cuong Dat
dc.contributor.authorDay, Craig S.
dc.contributor.authorOdena, Carlota
dc.contributor.authorBenet-Buchholz, Jordi
dc.contributor.authorXu, Liang
dc.contributor.authorForoutan-Nejad, Cina
dc.contributor.authorHopmann, Kathrin Helen
dc.contributor.authorMartin, Ruben
dc.date.accessioned2024-01-15T10:28:54Z
dc.date.available2024-01-15T10:28:54Z
dc.date.issued2022-07-13
dc.description.abstractHerein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)2Ni(0) species that are challenging to access otherwise.en_US
dc.identifier.citationDay, C.S., Do, C.D., Odena, C., Benet-Buchholz, J., Xu, L., Foroutan-Nejad, C., Hopmann, K.H. & Martin, R. (2022). Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction. <i>Journal of the American Chemical Society, 144</i>, 29, 13109-13117.en_US
dc.identifier.cristinIDFRIDAID 2202306
dc.identifier.doihttps://doi.org/10.1021/jacs.2c01807
dc.identifier.urihttps://hdl.handle.net/10037/32484
dc.language.isoengen_US
dc.publisherACS Publicationsen_US
dc.relation.projectIDNorges forskningsråd: 300769en_US
dc.relation.projectIDSigma2: nn4654ken_US
dc.relation.projectIDSigma2: nn9330ken_US
dc.relation.projectIDNordforsk: 85378en_US
dc.relation.projectIDNorges forskningsråd: 262695en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/754558/Spain/COFUND BIST PREDOCTORAL PROGRAMME/PREBIST/en_US
dc.relation.urihttps://pubs.acs.org/doi/10.1021/jacs.2c01807
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2023 The Author(s)en_US
dc.rights.urihttps://creativecommons.org/licenses/by/4.0en_US
dc.rightsAttribution 4.0 International (CC BY 4.0)en_US
dc.titleRoom Temperature-Stable Magnesium Electride via Ni(II) Reductionen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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Attribution 4.0 International (CC BY 4.0)
Except where otherwise noted, this item's license is described as Attribution 4.0 International (CC BY 4.0)