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dc.contributor.authorLejon, Tore
dc.contributor.authorGozhina, Olga Vladimirovna
dc.contributor.authorKhrustalev, Victor N.
dc.date.accessioned2012-11-27T08:53:39Z
dc.date.available2012-11-27T08:53:39Z
dc.date.issued2012
dc.description.abstractThe molecule of the title compound, C16H21BO2, comprises a chiral fused tricyclic system containing five-membered (1,3,2-dioxaborolane), six-membered (cyclohexane) and four-membered (cyclobutane) rings. The 1,3,2-dioxaborolane ring is almost planar (r.m.s. deviation = 0.035 Å), and the syn H and Me substituents at this ring are in an eclipsed conformation. The cyclohexane and cyclobutane rings adopt sofa and butterfly conformations, respectively. The B atom has a trigonal-planar configuration (sum of the bond angles = 360.0°). The phenyl ring is practically coplanar with the 1,3,2-dioxaborolane ring [dihedral angle between the ring planes = 1.96 (8)°]. The absolute structure was determined from the known configuration of (+)-pinanediol which was used in the synthesis. In the crystal, weak C-H...[pi](Ph) interactions occur.en
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online E68(2012) s. o3103en
dc.identifier.cristinIDFRIDAID 948892
dc.identifier.doidoi: 10.1107/S1600536812041712
dc.identifier.issn1600-5368
dc.identifier.urihttps://hdl.handle.net/10037/4635
dc.identifier.urnURN:NBN:no-uit_munin_4350
dc.language.isoengen
dc.publisherInternational Union of Crystallographyen
dc.rights.accessRightsopenAccess
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440::Physical chemistry: 443en
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440::Fysikalsk kjemi: 443en
dc.title(3aS,4S,6S,7aR)-hexahydro-3a,5,5-trimethyl-2-phenyl-4,6-methano-1,3,2-benzodioxaboroleen
dc.typeJournal articleen
dc.typeTidsskriftartikkelen
dc.typePeer revieweden


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