Phlorins have long remained underexplored relative to their fully conjugated counterparts, such as porphyrins, hydroporphyrins, and corroles. Herein, we have attempted to bridge that knowledge gap with a scalar-relativistic density functional theory (DFT) study of unsubstituted iridium and gold phlorin derivatives and a multitechnique experimental study of iridium-bispyridine and gold complexes of ...

Background: While study approaches have been directly associated with students’ academic performance, learning environment factors may play a more indirect role. The aim of this study was (i) to assess learning environment factors as predictors of students’ average exam grades, and (ii) whether study approaches mediated associations between learning environment factors and exam grades.<p> <p>Methods: ...

Universal formal education is a major global development goal. Yet hunter-gatherer communities have extremely low participation rates in formal schooling, even in comparison with other marginalized groups. Here, we review the existing literature to identify common challenges faced by hunter-gatherer children in formal education systems in the Global South. We find that hunter-gatherer children are ...

Herein, we report the direct carboxylation of unactivated secondary alkyl bromides enabled by the merger of photoredox and nickel catalysis, a previously inaccessible endeavor in the carboxylation arena. Site-selectivity is dictated by a kinetically controlled insertion of CO₂ at the initial C(sp³ )−Br site by the rapid formation of Ni(I)−alkyl species, thus avoiding undesired ...

Numerical climate model simulations suggest that global warming is enhanced or hampered by the spatial pattern of the warming itself. This phenomenon is known as the “pattern effect” and has in recent years become the most promising explanation for the change over time of climate sensitivity in climate models. Under historical global warming, different patterns of surface-temperature change have ...

Egg quality in fishes is commonly determined by fertilisation success and cleavage patterns as a phenotypic outcome of underlying regulatory mechanisms. Although these phenotypic estimators of egg quality are useful in farming conditions, these “good quality” egg batches do not always translate to good larval growth and survival. The identification of genes involved in embryonic development may help ...

Svalbard, located between 76°30′N and 80°50′N, is among the regions in the world with the most rapid temperature increase. We processed a cloud-free time-series of MODIS-NDVI for Svalbard. The dataset is interpolated to daily data during the 2000–2022 period with 232 m pixel resolution. The onset of growth, with a clear phenological definition, has been mapped each year. Then the integrated NDVI ...

In May–June 2019, the microalga Chrysochromulina leadbeateri caused a massive fish-killing event in several fjords in Northern Norway, resulting in the largest direct impact ever on aquaculture in northern Europe due to toxic algae. Motivated by the fact that no algal toxins have previously been described from C. leadbeateri, we set out to investigate the chemical nature and toxicity of secondary ...

Animals inhabiting temperate and high latitudes undergo drastic seasonal changes in energy storage, facilitated by changes in food intake and body mass. Those seasonal changes in the animal’s biology are not mere consequences of environmental energy availability but are anticipatory responses to the energetic requirements of the upcoming season and are actively timed by tracking the annual ...

Behavioural monitoring can provide crucial information on welfare and feeding in aquaculture. Passive acoustic monitoring of behaviour can be particularly useful in recirculating aquaculture systems (RAS), as they often have turbid water that impairs visual monitoring. Currently, little is known about the sounds that make up the soundscapes in RAS tanks holding Atlantic salmon (Salmo salar). ...