xploratory scalar-relativistic density functional theory (B3LYP*-D3/ZORA-STO-TZ2P) calculations have been used to examine the stability and bonding of pseudotetrahedral Group 8 (Fe, Ru, and Os) and Group 9 (Co, Rh, and Ir) terminal carbide complexes with dδ4 ground states and tripodal tris(N-heterocyclic-carbene) supporting ligands. The calculations predict relatively low adiabatic ionization ...

Multifrequency atomic force microscopy (AFM) enhances resolving power, provides extra contrast channels, and is equipped with a formalism to quantify material properties pixel by pixel. On the other hand, multifrequency AFM lacks the ability to extract and examine the profile to validate a given force model while scanning. We propose exploiting data-driven algorithms, i.e., machine learning packages, ...

The rapid weakening of snow layers that accumulate infiltrating liquid water is a well-known, but poorly quantified, mechanism for wet-snow slab avalanche formation. Therefore, quantifying this mechanical process is a crucial part of forecasting these snow avalanches accurately. Currently, studies do not agree on how snow strength should change as a function of volumetric liquid water content ( ) ...

Rapporten presenterer resultater fra siste feltsesong av forskningsutgravning av nausttufter på Nergården, Bjarkøy utført av Norges arktiske universitetsmuseum (UM) og Troms og Finnmark fylkeskommune i fire feltperioder (2019-2022). De samlede utgravningsresultatene danner et grunnlag for tolkning av konstruksjon, kronologi og relasjoner mellom tre stornaustbygninger; et opprinnelig jernaldernaust ...

Background Across healthcare systems, current health policies promote interprofessional teamwork. Compared to single-profession general practitioner care, interprofessional primary healthcare teams are expected to possess added capacity to care for an increasingly complex patient population. This study aims to explore patients’ experiences when their usual primary healthcare encounter with general ...

Una dificultad aparente para cualquier sistema que proponga procedimientos generativos en la formación de palabras es el hecho de que los diccionarios deben incluir muy frecuentemente algunas palabras complejas incluso cuando no tienen valores idiosincrásicos. Este artículo argumenta que el problema se disuelve cuando se atiende a dos hechos gramaticales: la selección se produce de un núcleo a ...

Objective: Developmental dysplasia of the hip (DDH) is a congenital condition affecting 2-3% of all infants. DDH increases the risk of osteoarthritis, is the cause of 30% of all total hip arthroplasties (THAs) in adults <40 years of age and can result in loss of life quality. Our aim was to explore the genetic background of DDH in order to improve diagnosis, management and longterm outcome.<p><p> ...

The prevention of memory decline requires better knowledge of biological markers. We studied the associations between kidney function biomarkers and memory decline (assessed with the Mini-Mental State Examination—MMSE) in elderly individuals without dementia (MMSE 24–30, age 60–74 years, n = 643, Arkhangelsk, Russia). Participants were divided by sex and into three groups according to the delayed ...

Background Myocardial infarction is likely to be experienced as a life-threatening and potentially traumatic event. Approximately one-third of patients with myocardial infarction experience clinically significant symptoms of anxiety/ depression. However, it is unclear how many of these patients experience these symptoms because of post-traumatic stress disorder (PTSD). We conducted a clinical screening ...

In this paper we discuss, complement and improve some Bennett type inequalities. In particular,we prove a new refinement of a Bennett type inequality using super quadracity argument.