Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates

Permanent link
https://hdl.handle.net/10037/14492
DOI
https://doi.org/10.1002/cplu.201800131
Thumbnail
View/Open
Accepted manuscript version (PDF)
Date
2018-04-06
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Author
Gevorgyan, Ashot; Mkrtchyan, Satenik; Grigoryan, Tatevik; Iaroshenko, Viktor O
Abstract
The use of water as a donor for hydrogen suitable for the reduction of several important classes of organic compounds is described. It is found that the reductive water splitting can be promoted by several metalloids among which silicon shows the best efficiency. The developed methodologies were applied for the reduction of nitro compounds, N‐oxides, sulfoxides, alkenes, alkynes, hydrodehalogenation as well as for the gram‐scale synthesis of several substrates of industrial importance.
Description
This is the peer reviewed version of the following article: Gevorgyan, A., Mkrtchyan, S., Grigoryan, T. & Iaroshenko, V.O. (2018). Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates. ChemPlusChem, 83(5), 375-382, which has been published in final form at https://doi.org/10.1002/cplu.201800131. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Publisher
Wiley
Citation
Gevorgyan, A., Mkrtchyan, S., Grigoryan, T. & Iaroshenko, V.O. (2018). Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates. ChemPlusChem, 83(5), 375-382. https://doi.org/10.1002/cplu.201800131
Metadata
Show full item record
Collections