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Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction

dc.contributor.authorDay, Craig S.
dc.contributor.authorDo, Cuong Dat
dc.contributor.authorOdena, Carlota
dc.contributor.authorBenet-Buchholz, Jordi
dc.contributor.authorXu, Liang
dc.contributor.authorForoutan-Nejad, Cina
dc.contributor.authorHopmann, Kathrin Helen
dc.contributor.authorMartin, Ruben
dc.date.accessioned2022-08-18T12:02:49Z
dc.date.available2022-08-18T12:02:49Z
dc.date.issued2022-07-13
dc.description.abstractHerein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, noncoordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)<sub>2</sub>Ni(0) species that are challenging to access otherwise.en_US
dc.identifier.citationDay, Do, Odena, Benet-Buchholz, Xu, Foroutan-Nejad, Hopmann, Martin. Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction. Journal of the American Chemical Society. 2022en_US
dc.identifier.cristinIDFRIDAID 2038367
dc.identifier.doi10.1021/jacs.2c01807
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.urihttps://hdl.handle.net/10037/26285
dc.language.isoengen_US
dc.publisherACS Publicationsen_US
dc.relation.journalJournal of the American Chemical Society
dc.relation.projectIDTromsø forskningsstiftelse: TFS2016KHHen_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/EXCELLENT SCIENCE /754558/EU/COFUND BIST PREDOCTORAL PROGRAMME/PREBIST/en_US
dc.relation.urihttps://pubs.acs.org/doi/full/10.1021/jacs.2c01807
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2022 The Author(s)en_US
dc.titleRoom-Temperature-Stable Magnesium Electride via Ni(II) Reductionen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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