Extreme space weather events are rare, and quantifying their likelihood is challenging, often relying on geomagnetic indices obtained from ground-based magnetometer observations that span multiple solar cycles. The Dst index ring-current monitor, derived from an hourly average over four low-latitude stations, is a benchmark for extreme space weather events, and has been extensively studied ...

DFT calculations with the well-tested OLYP and B3LYP* exchange-correlation functionals (along with D3 dispersion corrections and all-electron ZORA STO-TZ2P basis sets) and careful use of group theory have led to significant insights into the question of metal- versus ligand-centered redox in Co and Ni B,C-tetradehydrocorrin complexes. For the cationic complexes, both metals occur in their low-spin ...

Nares Strait and the channels of the Canadian Arctic Archipelago (CAA) act as conduits for sea ice export from the Arctic Ocean but have never been directly compared. Here, we perform such a comparison for both the sea ice area and volume fluxes from October 2016 to December 2021. Nares Strait provided the largest average seasonal (October through September) ice area flux of 95 ± 8 × 10³ ...

The application of artificial neural networks with the involvement of a modified homogeneity factor to predict exergetic terms from combustive and/or mixing dynamics in a marine engine is considered in this study. This is a significant step since the mathematical formulation of exergy in combustion is complicated and even unconvincing due to the turbulent and highly nonlinear nature of the combustion ...

Satellite observations of sea ice freeboard are integral to the estimation of sea ice thickness. It is commonly assumed that radar pulses from satellite-mounted Ku-band altimeters penetrate through the snow and reflect from the snow-ice interface. We would therefore expect a negative correlation between snow accumulation and radar freeboard measurements, as increased snow loading weighs the ice floe ...

The potential application of Lithium Niobate (LiNbO3) crystal is immense, specifically in the domain of metasurfaces and nano-resonators. However, the practical application of LiNbO₃ is impeded due to unreliable experimental techniques and inaccurate inversion algorithms for material characterization. In the current research, material characterization of anisotropic crystal is proposed ...

Quantum chemical calculations have for some time predicted that perfluorinated polyhedral organic molecules should exhibit a low-energy LUMO consisting of the overlapping inward-pointing lobes of the C−F σ* orbitals. Accordingly, these molecules should be able to encapsulate an electron within the interior of their cavities. Inspired by the recent confirmation of this prediction for perfluorocubane, ...

For passenger vessels operating in polar waters, the Polar Code requires that in case of possibility of immersion in polar waters, thermal protective immersion suits (TPIS) should be available for all passengers. Thus, international standards require that TPIS can be donned within 2 min and that walking speeds are reduced by no more than 25%. Clearlythese requirements are arbitrary and do not ...

Poly(ethylene terephthalate) polyester represents the most common class of thermoplastic polymers widely used in the textile, bottling, and packaging industries. Terephthalic acid and ethylene glycol, both of petrochemical origin, are polymerized to yield the polyester. However, an earlier report suggests that polymerization of methoxyterephthalic acid with ethylene glycol provides a methoxy-polyester ...

Current state-of-the-art infection and antimicrobial resistance (AMR) diagnostics are based on culture-based methods with a detection time of 48–96 h. Therefore, it is essential to develop novel methods that can do real-time diagnoses. Here, we demonstrate that the complimentary use of label-free optical assay with whole-genome sequencing (WGS) can enable rapid diagnosis of infection and AMR. Our ...