Extensive DFT calculations with several exchange–correlation functionals indicate that molybdenum-dichlorido Viking helmet corroles are noninnocent with significant Mo^IV-corrole^˙2− character. The effect is mediated by a Mo(4d)-corrole(π) orbital interaction similar to that postulated for MnCl, FeCl and FeNO corroles. The effect also appears to operate in tungsten-dichlorido ...

At present, most of the insurance claims in the offshore wind industry are due to cable failures where a large percentage occurs during the installation of the array and export cables. As the reliability of the cables depends on the location and installation method, it is important to map the risks involved, which can compromise the cable's integrity in individual projects. This paper presents ...

In September 2019, the German research icebreaker Polarstern started the largest multidisciplinary Arctic expedition, the MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) drift experiment. Being moored to ice floes at high Arctic for a whole year, thus including the winter season, the main goal of the expedition is to better understand and quantify relevant processes ...

Wind turbines’ economic and secure operation can be optimized through accurate ultra-short-term wind power and speed forecasts. Turbulence, considered as a local short-term physical wind phenomenon, affects wind power generation. This paper investigates the use of turbulence intensity for ultra-short-term predictions of wind power and speed with a wind farm in the Arctic, including and excluding ...

This paper documents the retrieval of significant ocean surface wave heights in the Arctic Ocean from CryoSat-2 data. We use a semi-analytical model for an idealised synthetic aperture satellite radar or pulse-limited radar altimeter echo power. We develop a processing methodology that specifically considers both the Synthetic Aperture and Pulse Limited modes of the radar that change close to ...

Fringe pattern analysis is the central aspect of numerous optical measurement methods, e.g., interferometry, fringe projection, digital holography, quantitative phase microscopy. Experimental fringe patterns always contain significant features originating from fluctuating environment, optical system and illumination quality, and the sample itself that severely affect analysis outcome. Before the ...

In a given country, the cumulative death toll of the first wave of the COVID-19 epidemic follows a sigmoid curve as a function of time. In most cases, the curve is well described by the Gompertz function, which is characterized by two essential parameters, the initial growth rate and the decay rate as the first epidemic wave subsides. These parameters are determined by socioeconomic factors and ...

The microbial key players at methane seeps are methanotrophic archaea and sulfate-reducing bacteria. They form spherical aggregates and jointly mediate the sulfate-dependent anaerobic oxidation of methane (SD–AOM: CH4 + SO42– → HCO3– + HS– + H2O), thereby inducing the precipitation of authigenic seep carbonates. While seep carbonates constitute valuable archives for molecular fossils of SD–AOM-mediating ...

Faults commonly form loci for high fluid flux in sedimentary basins, where fluids, rocks and deformation processes frequently interact. Here, we elucidate the interaction of fluid flow, diagenesis and deformation near basin-bounding faults in sedimentary basins through a study in the vicinity (0–3.5 km) of the Dombjerg Fault in the NE Greenland rift system. Due to fault-controlled fluid circulation, ...

A remaining carbon budget (RCB) estimates how much CO2 we can emit and still reach a specific temperature target. The RCB concept is attractive since it easily communicates to the public and policymakers, but RCBs are also subject to uncertainties. The expected warming levels for a given carbon budget has a wide uncertainty range, which increases with less ambitious targets, i.e., with higher CO2 ...