Acid-catalyzed condensation of pyrrole, 4-trifluoromethylbenzaldehyde, and azulene, followed by DDQ oxidation, has resulted in the isolation of the novel macrocycle azulicorrole, arguably the first example of a carbacorrole aside from N-confused corrole. Despite poor yields (<1%), the free ligand could be structurally characterized and converted to the formal Cu(III) and Au(III) derivatives, of which ...

A combination of quantum chemical calculations and synthetic studies was used to address the possibility of very high (>6) valence states of transition metals in porphyrin‐type complexes. With corrole as a supporting ligand, DFT calculations ruled out Re(VII) and Ir(VII) dioxo complexes as stable species. Attempted rhenium insertion into benzocarbaporphyrin (BCP) ligands on the other hand led to two ...

The atmospheric meridional energy transport in the Northern Hemisphere midlatitudes is mainly accomplished by planetary and synoptic waves. A decomposition into wave components highlights the strong seasonal dependence of the transport, with both the total transport and the contributions from planetary and synoptic waves peaking in winter. In both winter and summer months, poleward transport extremes ...

Blood analysis is an important diagnostic tool, as it provides a wealth of information about the patient's health. Raman spectroscopy is a promising tool for blood analysis, but widespread clinical application is limited by its low signal strength, as well as complex and costly instrumentation. The growing field of waveguide-based Raman spectroscopy tries to solve these challenges by working toward ...

<p>The work presented in this dissertation combines two fully independent approaches to achieve compound libraries for anticancer drug research. <p>Project 1: Development of compounds inhibiting human dUTPase as an amplifier of a thymidylate synthase inhibitor based cancer therapy <p>The human dUTPase has received increased attention as a drug target in the recent years. Its inhibition can ...

Solar flares provide strong impulsive radiation and energy injection to the sunlit upper atmosphere. The impact on the ionosphere is immense in spatial scale, and therefore, it is not immediately evident if dramatically elevated neutral heating can lead to excitation of acoustic gravity waves. Using primary observations from Global Navigation Satellite System differential TEC (total electron ...

Although the plankton communities in the Barents Sea have been intensely studied for decades, little is known about the living planktonic foraminiferal (LPF) and pteropod faunas, especially those found at methane seep sites. Along a repeated transect in the “crater area” (northern Barents Sea, 74.9°N, 27.7°E) in spring and summer 2016 the flux of LPF and of the pteropod species <i>Limacina helicina</i> ...

360∘ panorama video displayed through Virtual Reality (VR) glasses or large screens offers immersive user experiences, but as such technology becomes commonplace, the need for efficient streaming methods of such high-bitrate videos arises. In this respect, the attention that 360∘ panorama video has received lately is huge. Many methods have already been proposed, and in this paper, we shed more light ...

In this paper, we introduce a new approach for investigation of polarimetric Synthetic Aperture Radar (PolSAR) images for oil slick analysis. Our method aims at enhancing discrimination of oil types by exploring the polarimetric features that can be produced by processing PolSAR scenes without dimensionality reduction. Taking advantage of a mixture description of the interactions among classes within ...

Porphyrinoids are a family of molecules, which consist of large ring structures or macrocycles. One of the oldest, and most important, of the porphyrinoids is the biological molecule called porphyrin. Since the dawn of life, porphyrins have orchestrated photosynthesis and oxygen respiration, two of the most important energy-generating processes in nature. In addition to porphyrins, other porphyrinoids ...