The insertion of CO2 into metal alkyl bonds is a crucial elementary step in transition metal-catalyzed processes for CO2 utilization. Here, we synthesize pincer-supported palladium complexes of the type (tBuPBP)Pd(alkyl) (tBuPBP = B(NCH2PtBu2)2C6H4−; alkyl = CH2CH3, CH2CH2CH3, CH2C6H5, and CH2-4-OMe-C6H4) and (tBuPBP)Pd(C6H5) and compare the rates of CO2 insertion into the palladium alkyl bonds to ...

A rigorous forward model solver for conventional coherent microscope is presented. The forward model is derived from Maxwell’s equations and models the wave behaviour of light matter interaction. Vectorial waves and multiple-scattering effect are considered in this model. Scattered field can be calculated with given distribution of the refractive index of the biological sample. Bright field images ...

The interest in video anomaly detection systems that can detect different types of anomalies, such as violent behaviours in surveillance videos, has gained traction in recent years. The current approaches employ deep learning to perform anomaly detection in videos, but this approach has multiple problems. For example, deep learning in general has issues with noise, concept drift, explainability, ...

Extreme space weather events are rare, and quantifying their likelihood is challenging, often relying on geomagnetic indices obtained from ground-based magnetometer observations that span multiple solar cycles. The Dst index ring-current monitor, derived from an hourly average over four low-latitude stations, is a benchmark for extreme space weather events, and has been extensively studied ...

DFT calculations with the well-tested OLYP and B3LYP* exchange-correlation functionals (along with D3 dispersion corrections and all-electron ZORA STO-TZ2P basis sets) and careful use of group theory have led to significant insights into the question of metal- versus ligand-centered redox in Co and Ni B,C-tetradehydrocorrin complexes. For the cationic complexes, both metals occur in their low-spin ...

Nares Strait and the channels of the Canadian Arctic Archipelago (CAA) act as conduits for sea ice export from the Arctic Ocean but have never been directly compared. Here, we perform such a comparison for both the sea ice area and volume fluxes from October 2016 to December 2021. Nares Strait provided the largest average seasonal (October through September) ice area flux of 95 ± 8 × 10³ ...

The application of artificial neural networks with the involvement of a modified homogeneity factor to predict exergetic terms from combustive and/or mixing dynamics in a marine engine is considered in this study. This is a significant step since the mathematical formulation of exergy in combustion is complicated and even unconvincing due to the turbulent and highly nonlinear nature of the combustion ...

Satellite observations of sea ice freeboard are integral to the estimation of sea ice thickness. It is commonly assumed that radar pulses from satellite-mounted Ku-band altimeters penetrate through the snow and reflect from the snow-ice interface. We would therefore expect a negative correlation between snow accumulation and radar freeboard measurements, as increased snow loading weighs the ice floe ...

The potential application of Lithium Niobate (LiNbO3) crystal is immense, specifically in the domain of metasurfaces and nano-resonators. However, the practical application of LiNbO₃ is impeded due to unreliable experimental techniques and inaccurate inversion algorithms for material characterization. In the current research, material characterization of anisotropic crystal is proposed ...

Quantum chemical calculations have for some time predicted that perfluorinated polyhedral organic molecules should exhibit a low-energy LUMO consisting of the overlapping inward-pointing lobes of the C−F σ* orbitals. Accordingly, these molecules should be able to encapsulate an electron within the interior of their cavities. Inspired by the recent confirmation of this prediction for perfluorocubane, ...