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A highly asymmetric gold(III) η3‐allyl complex

dc.contributor.authorHolmsen, Marte Sofie
dc.contributor.authorNova, Ainara
dc.contributor.authorØien-Ødegaard, Sigurd
dc.contributor.authorHeyn, Richard H.
dc.contributor.authorTilset, Mats
dc.date.accessioned2020-01-24T10:24:58Z
dc.date.available2020-01-24T10:24:58Z
dc.date.issued2019-11-11
dc.description.abstractA highly asymmetric Au<sup>III</sup> η<sup>3</sup>‐allyl complex has been generated by treating Au(η<sup>1</sup>‐allyl)Br(tpy) (tpy=2‐(<i>p</i>‐tolyl)pyridine) with AgNTf<sub>2</sub>. The resulting η<sup>3</sup>‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature <sup>1</sup>H NMR suggest that the allyl ligand is highly fluxional.en_US
dc.identifier.citationHolmsen MS, Nova A, Øien-Ødegaard S, Heyn RH, Tilset M. A highly asymmetric gold(III) η3‐allyl complex. Angewandte Chemie International Edition. 2019:1-6en_US
dc.identifier.cristinIDFRIDAID 1778232
dc.identifier.doi10.1002/anie.201912315
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttps://hdl.handle.net/10037/17217
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.journalAngewandte Chemie International Edition
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/GASSMAKS/185513/Norway/New Gold Catalysts for the Activation and Functionalization of Alkanes//en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/FRINATEK/221801/Norway/Fundamental Studies of Gold(III) Complexes With Hydrocarbon Ligands//en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/FRINATEK/250044/Norway/Rational catalyst design for transforming CO2 into industrially attractive products: Formic acid, polycarbonates and polyurethanes//en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/SFF/262695/Norway/Hylleraas Centre for Quantum Molecular Sciences//en_US
dc.relation.projectIDinfo:eu-repo/grantAgreement/RCN/FORINFRA/226244/Norway/NNP - The Norwegian NMR Platform//en_US
dc.rights.accessRightsopenAccessen_US
dc.rights.holderCopyright 2019 The Author(s)en_US
dc.subjectVDP::Mathematics and natural science: 400::Chemistry: 440en_US
dc.subjectVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US
dc.titleA highly asymmetric gold(III) η3‐allyl complexen_US
dc.type.versionpublishedVersionen_US
dc.typeJournal articleen_US
dc.typeTidsskriftartikkelen_US
dc.typePeer revieweden_US


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