A highly asymmetric gold(III) η3‐allyl complex

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https://hdl.handle.net/10037/17217
DOI
https://doi.org/10.1002/anie.201912315
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Date
2019-11-11
Type
Journal article
Tidsskriftartikkel
Peer reviewed

Author
Holmsen, Marte Sofie; Nova, Ainara; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats
Abstract
A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature 1H NMR suggest that the allyl ligand is highly fluxional.
Publisher
Wiley
Citation
Holmsen MS, Nova A, Øien-Ødegaard S, Heyn RH, Tilset M. A highly asymmetric gold(III) η3‐allyl complex. Angewandte Chemie International Edition. 2019:1-6
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Copyright 2019 The Author(s)