Copper undecaarylcorroles were found to undergo acid-induced demetalation with unusual ease under both reductive and nonreductive conditions. The resulting free-base undecaarylcorroles were found to be rather reactive, readily photooxygenating to yield 5/10-hydroxyisocorroles and open-chain tetrapyrroles. The use of nonreductive conditions led to 50-75% yields of undecaarylisocorroles, a new class ...

The climate system approaches a tipping point if the prevailing climate state loses stability, making a transition to a different state possible. A result from the theory of randomly driven dynamical systems is that the reduced stability in the vicinity of a tipping point is accompanied by increasing fluctuation levels and longer correlation times (critical slowing down) and can in principle serve ...

The description of chemical phenomena in solution is as challenging as it is im- portant for the accurate calculation of molecular properties. Here, we present the implementation of the polarizable continuum model (PCM) in the four-component Dirac–Kohn–Sham density functional theory framework, o ↵ ering a cost-e ↵ ective way to concurrently model solvent and relativistic e ↵ ects. The ...

We have estimated the seismic attenuation in gas hydrate and free-gas-bearing sediments from high-resolution P-cable 3D seismic data from the Vestnesa Ridge on the Arctic continental margin of Svalbard. P-cable data have a broad bandwidth (20–300 Hz), which is extremely advantageous in estimating seismic attenuation in a medium. The seismic quality factor (Q), the inverse of seismic attenuation, ...

Little is known about the production of fluorescent dissolved organic matter (FDOM) in the anoxic oceanic sediments. In this study, sediment pore waters were sampled from four different sites in the Chukchi-East Siberian Seas area to examine the bulk dissolved organic carbon (DOC) and their optical properties. The production of FDOM, coupled with the increase of nutrients, was observed above the ...

The mesopause region can be considered a "boundary region" between the neutral atmosphere, where atmospheric constituents and momentum are transported mainly by winds and turbulent eddies, and the ionosphere, where the main transport mechanism is molecular diffusion. In the mesopause, complex interactions between dynamics and photochemistry occur, and we are far from a complete understanding of these ...

This thesis focuses on metallo-β-lactamases (MBLs) enzymes that break down a wide variety of antibiotics. Bacteria harboring genes expressing MBLs are antibiotic resistant. If the MBL genes are found on mobile genetic elements, the spread of the genes between bacteria becomes easier. To date, there are no MBL inhibitors available for blocking the enzyme activity, and thus there is an urgent need to ...

Late Early Permian–lowermost Triassic carbonate, siliceous (spiculites) and clastic marine sediments in the Marmierfjellet area (Isfjorden, central Spitsbergen) contain a relatively diverse and abundant trace fossil assemblage providing important information about the depositional processes. The Vøringen Member (Late Artinskian–Kungurian) of the Kapp Starostin Formation (Late Artinskian–? Changhsingian) ...

Background The glucuronoyl esterase enzymes of wood-degrading fungi (Carbohydrate Esterase family 15; CE15) form part of the hemicellulolytic and cellulolytic enzyme systems that break down plant biomass, and have possible applications in biotechnology. Homologous enzymes are predicted in the genomes of several bacteria, however these have been much less studied than their fungal counterparts. ...

Gas hydrates stored on continental shelves are susceptible to dissociation triggered by environmental changes. Knowledge of the timescales of gas hydrate dissociation and subsequent methane release are critical in understanding the impact of marine gas hydrates on the ocean–atmosphere system. Here we report a methane efflux chronology from five sites, at depths of 220–400 m, in the southwest Barents ...