Given the many applications of ruthenium porphyrins, the rarity of ruthenium corroles and the underdeveloped state of their chemistry are clearly indicative of an area ripe for significant breakthroughs. The tendency of ruthenium corroles to form unreactive metal–metal-bonded dimers has been recognized as a key impediment in this area. Herein, by exposing free-base meso-tris(p-X-phenyl)corroles, ...

<p>Devices for observing the environment range from basic sensor systems, like step-counters, through wild-life cameras, with limited processing capabilities, to more capable devices with significant processing, memory and storage resources. Individual usage domains can benefit from a range of functionalities in these devices including flexibility in prototyping, on- device analytics, network roaming, ...

The delivery of surface meltwater through englacial drainage systems to the bed of the Greenland Ice Sheet modulates ice flow through basal lubrication. Recent studies in Southeast Greenland have identified a perennial firn aquifer; however, there are few observations quantifying the input or residence time of water within the englacial system and it remains unknown whether water can be stored within ...

Air-, surface-, and subsurface temperatures were recorded by automatic weather stations in Bliss Bugt and Moore Gletscher, Johannes V. Jensen Land, North coast of Greenland from 2006-2010. The mean annual surface temperature is -12.1 ℃ in Bliss Bugt and -13.8 ℃ at Moore Gletscher. In 20 cm depth below the surface at Moore Gletscher, the mean annual temperature is -13.2 ℃ (2007-2008). High-amplitude ...

In this paper we propose a new test statistic for unsupervised changedetectioninpolarimetricsyntheticapertureradar(PolSAR) data. We work with multilook complex (MLC) covariance matrix data, whose underlying model is assumed to be the scaled complex Wishart distribution. We use the complex kind Hotelling-Lawley (HL) trace statistic for measuring the similarity of two covariance matrices. The sampling ...

<p>Multiple proxies in the geological record offshore NW Svalbard track shallow subseafloor diagenesis and seafloor methane seepage during the Last Glacial Maximum (LGM) extent and the disintegration of the Svalbard Barents Sea Ice Sheet (SBIS). Vestnesa Ridge, located at 79°N and in 1200 m water depth, is one of the northernmost known active methane seep sites and is characterised by a subseafloor ...

Living (Rose Bengal stained) benthic foraminifera were studied in the topmost sediments of five multi- and box cores collected on the continental shelf, upper and lower slopes, of the Chukchi Sea to provide background information on modern benthic foraminiferal distribution, useful for future studies. Sediment cores were collected during August–September 2015, when the area is seasonally ice-free. ...

Arctic and Antarctic polynyas are crucial sites for deep-water formation, which helps sustain global ocean circulation. During glacial times, the occurrence of polynyas proximal to expansive ice sheets in both hemispheres has been proposed to explain limited ocean ventilation and a habitat requirement for marine and higher-trophic terrestrial fauna. Nonetheless, their existence remains equivocal, ...

The dimensions of mitochondria are close to the diffraction limit of conventional light microscopy techniques, making the complex internal structures of mitochondria unresolvable. In recent years, new fluorescence-based optical imaging techniques have emerged, which allow for optical imaging below the conventional limit, enabling super-resolution (SR). Possibly the most promising SR and diffraction-limited ...

Arctic Ocean trough mouth fans (TMFs) represent a valuable archive of glacial-interglacial sedimentary processes that are especially important when reconstructing pre-Weichselian glaciations that may lack distinct imprints on the shelves. In 2011, we acquired the first high-resolution 3D seismic cube (~3 m vertical and 6 m horizontal resolution) on the continental slope of the SW Barents Sea by use ...